The results of the non-invasive in situ campaign on paintings by Vittore Grubicy  at the Fondazione Livorno were presented during the 11th International Conference “ART’14” (“Non-Destructive Investigations and Microanalysis for the Diagnostics and Conservation of Cultural and Environmental Heritage”) in Madrid. Francesca Gabrieli presented the results of the study reconstructing the composition of the stratigraphy of five paintings; the point-like analysis were performed with XRF, FTIR, Raman, XRD and UV-VIS instruments.